Buhar Basıncı ve Kaynama Noktası
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Buhar basıncının sıcaklıkla nasıl değiştiğini ölçme
Hedef
Suyun farklı sıcaklıklardaki buhar basıncını ölçmek ve Clausius-Clapeyron denklemini doğrulamak.
Arka Plan
The vapor pressure of a liquid increases exponentially with temperature. By measuring the temperature at which water boils under different reduced pressures (or measuring vapor pressure at different temperatures), the enthalpy of vaporization can be determined from the Clausius-Clapeyron equation.
Güvenlik Uyarıları
- Handle vacuum apparatus carefully — implosion risk with glass
- Hot water can cause burns
- Use proper vacuum-rated glassware only
Gerekli KKD
Malzemeler
-
Distilled water (200 mL)
-
Ice (500 g)For cold water bath
Ekipman
Prosedür
Set up the flask with water, thermometer, and pressure gauge. Connect to the vacuum pump.
Heat the water to 80°C. Record the temperature and vapor pressure.
Reduce pressure with the vacuum pump. Note the temperature at which boiling begins.
Record at least 8 temperature-pressure data points from 40°C to 100°C.
Plot ln(P) vs 1/T(K). The slope = -ΔHvap/R.
Calculate ΔHvap from the slope. Compare with the literature value of 40.7 kJ/mol.
Beklenen Sonuçlar
The ln(P) vs 1/T plot should be linear with a negative slope. The calculated ΔHvap should be approximately 40-44 kJ/mol, close to the accepted value of 40.7 kJ/mol for water.
Temizlik
Release vacuum slowly. Turn off heater. Drain water and dry apparatus.
Ayrıntılar
- Kategori
- Gas Laws
- Zorluk
- Advanced (University)
- Süre
- 45 dak
- Tahmini Maliyet
- $12,00
- Adımlar
- 6
- Malzemeler
- 2