Contact Process SO₂ Oxidation
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2SO2 + O2 ⇌ 2SO3
Genel Bakış
Sulfur dioxide is oxidized to sulfur trioxide over a vanadium pentoxide catalyst in the contact process for sulfuric acid manufacture. Sulfur changes from +4 to +6 oxidation state. The equilibrium is favored by low temperature but requires high temperature for adequate reaction rate, so 400-450 C with V₂O₅ catalyst provides optimal yield.
Katılımcılar
| Rol | Madde | Katsayı | Hal |
|---|---|---|---|
| Reaktan | Oxygen O | 1 | (g) |
| Reaktan | Sulfur Dioxide SO₂ | 2 | (g) |
| Ürün | Sulfur Trioxide SO₃ | 2 | (g) |
Günlük Örnek
Sulfuric acid produced by this process is the world's most produced chemical, used in everything from fertilizers to batteries to detergents.
Endüstriyel Önemi
The contact process produces over 260 million tonnes of sulfuric acid annually. V₂O₅ catalyst replaced the original, more expensive platinum catalyst.
Özellikler
- Tür
- Redox
- Geri Dönüşümlü
- Evet
- Enerji
- Ekzotermik
- ΔH
- -198,0 kJ/mol
- Katalizör
- Vanadium(V) oxide (V₂O₅)