Reduction of Manganese Dioxide by HCl
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MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O
Genel Bakış
Manganese dioxide oxidizes hydrochloric acid to produce chlorine gas, with Mn(IV) being reduced to Mn(II). Two of the four HCl molecules are oxidized (Cl⁻ → Cl₂) while two provide the acid environment. This was historically the main method for chlorine gas production before the chlor-alkali process.
Katılımcılar
| Rol | Madde | Katsayı | Hal |
|---|---|---|---|
| Reaktan | Hydrochloric Acid HCl | 4 | (aq) |
| Ürün | Chlorine Cl | 1 | (g) |
| Ürün | Water H₂O | 2 | (l) |
Günlük Örnek
This was the reaction Carl Wilhelm Scheele used to discover chlorine gas in 1774, calling it dephlogisticated muriatic acid.
Endüstriyel Önemi
Before electrolysis, this was the primary industrial method for chlorine production. It remains a standard lab preparation for small amounts of chlorine gas.
Özellikler
- Tür
- Redox
- Geri Dönüşümlü
- Hayır
- Enerji
- Ekzotermik
- ΔH
- -35,0 kJ/mol