Hydrogen Sulfide Oxidation by Chlorine
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H2S + Cl2 → 2HCl + S
Übersicht
Chlorine oxidizes hydrogen sulfide to elemental sulfur while being reduced to hydrochloric acid. Sulfur is oxidized from -2 to 0. This reaction is used in removing hydrogen sulfide from natural gas (sweetening) and in treating hydrogen sulfide-containing wastewater.
Teilnehmer
| Rolle | Substanz | Koeffizient | Zustand |
|---|---|---|---|
| Reaktant | Hydrogen Sulfide H₂S | 1 | (g) |
| Reaktant | Chlorine Cl | 1 | (g) |
| Produkt | Sulfur S | 1 | (s) |
| Produkt | Hydrochloric Acid HCl | 2 | (g) |
Alltägliches Beispiel
The rotten egg smell of hydrogen sulfide from sewers can be eliminated by chlorination, which oxidizes H₂S to odorless elemental sulfur.
Industrielle Bedeutung
H₂S removal by chlorine oxidation is used in natural gas sweetening, wastewater treatment, and in the petroleum refining industry.
Eigenschaften
- Typ
- Redox
- Reversibel
- Nein
- Energie
- Exotherm
- ΔH
- -186,0 kJ/mol