Manganese Dioxide Precipitation
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MnSO4 + 2NaOH + H2O2 → MnO2↓ + Na2SO4 + 2H2O
Übersicht
Manganese(II) sulfate is oxidized by hydrogen peroxide in basic solution to form a dark brown precipitate of manganese dioxide. Mn is oxidized from +2 to +4. MnO₂ is highly insoluble and is a very effective catalyst for H₂O₂ decomposition.
Teilnehmer
| Rolle | Substanz | Koeffizient | Zustand |
|---|---|---|---|
| Reaktant | Hydrogen Peroxide H₂O₂ | 1 | (aq) |
| Reaktant | Sodium Hydroxide NaOH | 2 | (aq) |
| Produkt | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
| Produkt | Water H₂O | 2 | (l) |
Alltägliches Beispiel
MnO₂ is the black substance in standard alkaline batteries that serves as the cathode material.
Industrielle Bedeutung
Manganese dioxide is used in dry cell and alkaline batteries, as a catalyst, as a pigment, and in water treatment for iron and manganese removal.
Eigenschaften
- Typ
- Precipitation
- Reversibel
- Nein
- Energie
- Exotherm
- ΔH
- -200,0 kJ/mol