Silver Chloride Precipitation
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AgNO3 + NaCl → AgCl↓ + NaNO3
Übersicht
Silver nitrate reacts with sodium chloride to form a white curdy precipitate of silver chloride. AgCl has a very low Ksp of 1.8 × 10⁻¹⁰, making it essentially insoluble. The precipitate turns purple in light due to photodecomposition of AgCl to silver metal and chlorine. This is the basis of the chloride ion test.
Teilnehmer
| Rolle | Substanz | Koeffizient | Zustand |
|---|---|---|---|
| Reaktant | Silver Nitrate AgNO₃ | 1 | (aq) |
| Reaktant | Sodium Chloride NaCl | 1 | (aq) |
| Produkt | Silver Chloride AgCl | 1 | (s) |
| Produkt | Sodium Nitrate NaNO₃ | 1 | (aq) |
Alltägliches Beispiel
The silver chloride test for chloride ions in water is one of the first qualitative analysis tests taught in chemistry courses.
Industrielle Bedeutung
AgCl precipitation is used in water quality testing, photography (historical), and in the preparation of silver chloride electrodes for electrochemistry.
Eigenschaften
- Typ
- Precipitation
- Reversibel
- Nein
- Energie
- Exotherm
- ΔH
- -65,5 kJ/mol