Photocatalytic Water Splitting (TiO₂)
2H2O → 2H2 + O2
ภาพรวม
Titanium dioxide absorbs UV light and generates electron-hole pairs that can split water into hydrogen and oxygen. Discovered by Fujishima and Honda in 1972, this reaction is the basis of artificial photosynthesis research. The bandgap of TiO₂ (3.2 eV) limits absorption to UV, so researchers are developing visible-light photocatalysts.
ผู้เข้าร่วม
| บทบาท | สาร | สัมประสิทธิ์ | สถานะ |
|---|---|---|---|
| สารตั้งต้น | Water H₂O | 2 | (l) |
ตัวอย่างในชีวิตประจำวัน
Self-cleaning glass windows are coated with TiO₂ that photocatalytically decomposes organic dirt when exposed to sunlight.
ความสำคัญทางอุตสาหกรรม
Photocatalytic water splitting could produce green hydrogen fuel from sunlight and water, a key goal of renewable energy research.
คุณสมบัติ
- ประเภท
- Photochemical
- ย้อนกลับได้
- ไม่
- พลังงาน
- ดูดความร้อน
- ΔH
- 572.0 kJ/mol
- ตัวเร่งปฏิกิริยา
- TiO₂ (titanium dioxide)
ปฏิกิริยาที่เกี่ยวข้อง
Cis-Trans Isomerization of Retinal
Silver Chloride Photodecomposition
Luminol Chemiluminescence
Firefly Bioluminescence (Luciferin Oxidation)
Photolysis of Water (Vacuum UV)
Photochemical Smog Formation (NO₂ Photolysis)
Photodegradation of Methylene Blue by TiO₂
Photodissociation of Chlorine Gas
Silver Bromide Photodecomposition
Chlorophyll Fluorescence
Frequently Asked Questions
What is the equation for Photocatalytic Water Splitting (TiO₂)?
The balanced equation is: 2H₂O → 2H₂ + O₂.
What type of reaction is Photocatalytic Water Splitting (TiO₂)?
Photocatalytic Water Splitting (TiO₂) is a photochemical reaction.
Is Photocatalytic Water Splitting (TiO₂) exothermic or endothermic?
Photocatalytic Water Splitting (TiO₂) is endothermic (absorbs energy). The enthalpy change (ΔH) is 572.0 kJ/mol.
What conditions are needed for Photocatalytic Water Splitting (TiO₂)?
This reaction requires a catalyst (TiO₂ (titanium dioxide)).