Lithiumgewinnung aus Sole für die Batterieproduktion
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Gewinnung des leichtesten Metalls aus Salzflächen und Geothermalwässern
Übersicht
Lithium is extracted from continental brines (salt flats in Chile, Argentina, Bolivia — the 'Lithium Triangle') by solar evaporation and chemical precipitation, or from hard-rock spodumene ore (Australia) by acid roasting. Lithium demand is surging due to lithium-ion batteries for EVs and energy storage. Brine extraction accounts for about 50% of global production and is lower cost, while spodumene processing is faster but more energy-intensive. Battery-grade lithium carbonate or lithium hydroxide requires >99.5% purity.
Chemischer Prozess
For brine: Lithium-bearing brine (200-2,000 ppm Li) is pumped to evaporation ponds where solar evaporation over 12-18 months concentrates lithium to 6,000+ ppm while NaCl and KCl crystallize out. Magnesium is removed by lime addition, and lithium carbonate is precipitated by adding soda ash (Na₂CO₃) at 90 degrees C. The precipitate is filtered, washed, and dried to battery-grade specification.
MgCl₂ + Ca(OH)₂ → Mg(OH)₂↓ + CaCl₂ (magnesium removal)
Li₂CO₃ + Ca(OH)₂ → 2LiOH + CaCO₃ (causticization to lithium hydroxide)
Rohstoffe
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Lithium-bearing brine — Salt flats (Atacama, Hombre Muerto, Uyuni) (Lithium source (200-2,000 ppm Li))
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Soda ash (Na₂CO₃) — Solvay process or trona mining (Lithium precipitation agent)
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Calcium hydroxide (Ca(OH)₂) — Lime kiln (Magnesium removal agent)
Endprodukte
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Battery-grade lithium carbonate (Li₂CO₃) — NMC and LFP cathode production (>99.5% purity, <10 ppm Na, <5 ppm Fe)
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Battery-grade lithium hydroxide (LiOH·H₂O) — High-nickel NMC cathode production (>56.5% LiOH, required for NMC 811)
Environmental Impact
Brine evaporation consumes vast amounts of water in the world's driest regions, creating tension with local communities and ecosystems. Evaporation ponds cover hundreds of hectares. Spodumene processing requires energy-intensive acid roasting at 250 degrees C. Direct lithium extraction (DLE) technologies promise 90% less water use and land footprint.
Sicherheitshinweise
- ⚠ Lithium compounds are irritating to skin and eyes
- ⚠ Brine contains boron, arsenic, and other toxic elements
- ⚠ Sulfuric acid used in spodumene processing is corrosive
- ⚠ Lime and soda ash dust cause respiratory irritation
Neuere Innovationen
Direct lithium extraction (DLE) using ion-exchange, adsorption, or membrane technologies can extract lithium from dilute brines in hours instead of months, with much lower water consumption.
Lithium extraction from geothermal brines provides both clean energy and lithium.
Recycling of end-of-life EV batteries is expected to provide 10-20% of lithium supply by 2035.
Produktionsmaßstab
130000
Tonnen/Jahr
$25 billion
Marktwert
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