Verbrennung von Magnesium in Trockeneis
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Magnesium verbrennt in festem Kohlendioxid und reduziert CO₂ zu Kohlenstoff
Ziel
Demonstrieren, dass Magnesium Kohlendioxid reduzieren kann, und damit die Fehlvorstellung widerlegen, dass CO₂ Feuer immer löscht.
Hintergrund
Magnesium burns so intensely (over 3000°C) that it can reduce carbon dioxide to elemental carbon. When a burning magnesium ribbon is placed in a cavity carved into dry ice (solid CO₂), it continues to burn brilliantly white, producing magnesium oxide (white powder) and elemental carbon (black specks). This reaction (2Mg + CO₂ → 2MgO + C) dramatically shows that CO₂ is not always an effective fire extinguisher and that thermodynamic favorability depends on the specific reactants involved.
Sicherheitswarnungen
- Burning magnesium is extremely bright — never look directly at it without shade protection
- Dry ice causes frostbite on contact — never handle with bare hands
- Perform behind a safety shield
- Keep a fire-resistant mat underneath
- Do not attempt to extinguish burning Mg with water — explosion risk
- Ensure ventilation — CO₂ accumulation in enclosed spaces is dangerous
Erforderliche PSA
Materialien
-
Magnesium ribbon (30 cm)Clean, bright surface
-
Dry ice block (1 kg)Solid CO₂ (−78.5°C)
-
Tongs (long-handled) (1)For handling dry ice
Ausrüstung
Durchführung
Using tongs, carve a small cavity (about 3 cm deep) in the dry ice block. Place the dry ice on a fire-resistant mat.
Set up the safety shield between the demonstration and the audience. Distribute welding goggles or instruct everyone to look away when ignited.
Light one end of the magnesium ribbon. Once burning, quickly place it in the dry ice cavity using tongs.
Place another piece of dry ice on top to create a CO₂ atmosphere around the burning magnesium.
Observe: the magnesium continues to burn with an intense white flame inside the CO₂ environment. It does NOT go out.
After the reaction, examine the residue: white MgO powder and black carbon specks. Discuss the reaction: 2Mg + CO₂ → 2MgO + C.
Discuss implications for fire safety: why Mg fires cannot be extinguished with CO₂, water, or standard fire extinguishers.
Erwartete Ergebnisse
The magnesium continues to burn brilliantly inside the dry ice. After the reaction, white MgO and black carbon specks are visible in the dry ice cavity. This proves CO₂ has been reduced to elemental carbon.
Aufräumen
Allow all residues to cool and dry ice to sublimate. Sweep up MgO and carbon residue. No chemical waste disposal needed.
Details
- Kategorie
- Classroom Demonstrations
- Schwierigkeit
- Advanced (University)
- Dauer
- 25 Min.
- Geschätzte Kosten
- $15,00
- Schritte
- 7
- Materialien
- 3