Sulfuric Acid and Calcium Carbonate
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H2SO4 + CaCO3 → CaSO4 + H2O + CO2
Übersicht
Sulfuric acid reacts with calcium carbonate to form calcium sulfate, water, and carbon dioxide. Unlike HCl, this reaction can be self-limiting because the insoluble calcium sulfate coats the limestone surface, slowing further reaction. This is why HCl is preferred over H₂SO₄ for dissolving limestone.
Teilnehmer
| Rolle | Substanz | Koeffizient | Zustand |
|---|---|---|---|
| Reaktant | Calcium Carbonate CaCO₃ | 1 | (s) |
| Reaktant | Sulfuric Acid H₂SO₄ | 1 | (aq) |
| Produkt | Carbon Dioxide CO₂ | 1 | (g) |
| Produkt | Water H₂O | 1 | (l) |
| Produkt | Calcium Sulfate CaSO₄ | 1 | (s) |
Alltägliches Beispiel
Acid rain containing sulfuric acid damages limestone buildings and marble statues through this reaction, causing surface erosion over decades.
Industrielle Bedeutung
This reaction is relevant to acid rain damage assessment, flue gas desulfurization (wet limestone scrubbing), and phosphoric acid production from phosphate rock.
Eigenschaften
- Typ
- Acid-Base
- Reversibel
- Nein
- Energie
- Exotherm
- ΔH
- -26,0 kJ/mol