Aqua Regia Dissolving Gold
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Au + 3HCl + HNO3 → HAuCl4 + NO + 2H2O
Ikhtisar
Aqua regia (3:1 mixture of HCl and HNO₃) dissolves gold, which is inert to either acid alone. Nitric acid oxidizes gold to Au³⁺ while hydrochloric acid provides chloride ions that stabilize the gold as [AuCl₄]⁻ complex. The synergy between the two acids makes aqua regia effective against noble metals.
Peserta
| Peran | Zat | Koefisien | Keadaan |
|---|---|---|---|
| Reaktan | Gold Au | 1 | (s) |
| Reaktan | Nitric Acid HNO₃ | 1 | (aq) |
| Reaktan | Hydrochloric Acid HCl | 3 | (aq) |
| Produk | Water H₂O | 2 | (l) |
Contoh Sehari-hari
During WWII, George de Hevesy dissolved the Nobel Prize gold medals of Max von Laue and James Franck in aqua regia to hide them from the Nazis.
Pentingnya dalam Industri
Aqua regia is used in gold refining, analytical chemistry for dissolving noble metals, and in recovering precious metals from electronic waste.
Sifat
- Jenis
- Redox
- Dapat Dibalik
- Tidak
- Energi
- Eksoterm
- ΔH
- -150,0 kJ/mol