Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)
PbO2 + Pb + 2H2SO4 → 2PbSO4 + 2H2O
ภาพรวม
During discharge, lead dioxide (cathode, Pb⁴⁺) is reduced to lead sulfate while lead metal (anode, Pb⁰) is oxidized to lead sulfate. Both electrodes convert to PbSO₄, and the sulfuric acid electrolyte is consumed. The cell potential is 2.05 V. Charging reverses the reaction.
ผู้เข้าร่วม
| บทบาท | สาร | สัมประสิทธิ์ | สถานะ |
|---|---|---|---|
| สารตั้งต้น | Lead Pb | 1 | (s) |
| สารตั้งต้น | Sulfuric Acid H₂SO₄ | 2 | (aq) |
| ผลิตภัณฑ์ | Water H₂O | 2 | (l) |
ตัวอย่างในชีวิตประจำวัน
Every car battery is a lead-acid battery using this reversible redox reaction. Starting your car draws hundreds of amps from this reaction.
ความสำคัญทางอุตสาหกรรม
Lead-acid batteries represent a $40+ billion global industry used in vehicles, UPS systems, and energy storage. Over 99% of lead-acid batteries are recycled.
คุณสมบัติ
- ประเภท
- Redox
- ย้อนกลับได้
- ใช่
- พลังงาน
- คายความร้อน
- ΔH
- -359.4 kJ/mol
ปฏิกิริยาที่เกี่ยวข้อง
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)?
The balanced equation is: PbO₂ + Pb + 2H₂SO₄ → 2PbSO₄ + 2H₂O.
What type of reaction is Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)?
Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) is a redox reaction. It is reversible under certain conditions.
Is Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) exothermic or endothermic?
Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) is exothermic (releases energy). The enthalpy change (ΔH) is -359.4 kJ/mol.