Photochemical Cycloaddition ([2+2])

2 CH2=CH2 → Cyclobutane

अवलोकन

UV light promotes one alkene to its excited state, allowing a symmetry-forbidden [2+2] cycloaddition that cannot occur thermally according to the Woodward–Hoffmann rules. The product is a cyclobutane ring. This is a textbook example of how photochemistry enables reactions impossible by thermal pathways.

प्रतिभागी

भूमिका पदार्थ गुणांक अवस्था
अभिकारक Ethylene C₂H₄ 2 (g)

रोजमर्रा का उदाहरण

UV-induced [2+2] cycloaddition between adjacent thymine bases in DNA creates cyclobutane pyrimidine dimers, the main cause of sunburn.

औद्योगिक महत्व

[2+2] photocycloaddition is used in organic synthesis to construct strained ring systems and in the synthesis of natural products and pharmaceuticals.

गुण

प्रकार
Photochemical
प्रतिवर्ती
नहीं
ऊर्जा
ऊष्माक्षेपी
ΔH
-109.0 kJ/mol

संबंधित अभिक्रियाएँ

Cis-Trans Isomerization of Retinal Silver Chloride Photodecomposition Luminol Chemiluminescence Firefly Bioluminescence (Luciferin Oxidation) Photolysis of Water (Vacuum UV) Photochemical Smog Formation (NO₂ Photolysis) Photodegradation of Methylene Blue by TiO₂ Photodissociation of Chlorine Gas Silver Bromide Photodecomposition Chlorophyll Fluorescence

Frequently Asked Questions

What is the equation for Photochemical Cycloaddition ([2+2])?
The balanced equation is: 2 CH₂=CH₂ → Cyclobutane.
What type of reaction is Photochemical Cycloaddition ([2+2])?
Photochemical Cycloaddition ([2+2]) is a photochemical reaction.
Is Photochemical Cycloaddition ([2+2]) exothermic or endothermic?
Photochemical Cycloaddition ([2+2]) is exothermic (releases energy). The enthalpy change (ΔH) is -109.0 kJ/mol.