Electrolytic Manganese Dioxide Production
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MnSO4 + 2H2O → MnO2 + H2SO4 + H2
अवलोकन
Electrolytic manganese dioxide (EMD) is produced by electrolyzing manganese sulfate solution in sulfuric acid at 90–98°C. MnO₂ deposits on the titanium anode as a dense, high-purity gamma-phase material with superior electrochemical activity compared to natural or chemical MnO₂. EMD is essential for high-performance alkaline and lithium batteries.
प्रतिभागी
| भूमिका | पदार्थ | गुणांक | अवस्था |
|---|---|---|---|
| अभिकारक | Water H₂O | 2 | (l) |
| उत्पाद | Manganese Dioxide MnO₂ | 1 | (s) |
| उत्पाद | Sulfuric Acid H₂SO₄ | 1 | (aq) |
रोजमर्रा का उदाहरण
The MnO₂ cathode in every Duracell or Energizer alkaline battery is electrolytic manganese dioxide made by this process.
औद्योगिक महत्व
EMD production exceeds 500,000 tonnes annually, driven by demand from the alkaline and lithium battery industries.
गुण
- प्रकार
- Electrochemical
- प्रतिवर्ती
- नहीं
- ऊर्जा
- ऊष्माशोषी
- ΔH
- 385.0 kJ/mol