Ostwald Process NO Oxidation
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4NH3 + 5O2 → 4NO + 6H2O
Aperçu
Ammonia is catalytically oxidized to nitric oxide over a platinum-rhodium gauze catalyst at about 850 C in the Ostwald process. Nitrogen is oxidized from -3 in NH₃ to +2 in NO. The NO is further oxidized to NO₂ and absorbed in water to make nitric acid. This process links the Haber process to nitric acid production.
Participants
Exemple du quotidien
Nearly all explosives, from TNT to ammonium nitrate, begin with nitric acid produced by this catalytic oxidation of ammonia.
Importance industrielle
The Ostwald process produces virtually all the world's nitric acid, essential for fertilizers (ammonium nitrate), explosives, and chemical manufacturing.
Propriétés
- Type
- Redox
- Réversible
- Non
- Énergie
- Exothermique
- ΔH
- -905,0 kJ/mol
- Catalyseur
- Platinum-rhodium gauze