विघटन हमेशा ऊष्माक्षेपी नहीं होता
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विभिन्न लवण विघटनों के तापमान परिवर्तनों की तुलना
उद्देश्य
यह दिखाने के लिए कि विघटन ऊष्माक्षेपी या ऊष्माशोषी हो सकता है, विभिन्न लवणों (NaOH, CaCl₂, NH₄NO₃, KNO₃) की विघटन एन्थैल्पी की तुलना करें।
पृष्ठभूमि
Students often assume dissolving always releases heat. This experiment tests four salts: NaOH and CaCl₂ dissolve exothermically (temperature rises), while NH₄NO₃ and KNO₃ dissolve endothermically (temperature drops). The results illustrate that lattice energy vs hydration energy determines the sign of ΔH.
सुरक्षा चेतावनियाँ
- NaOH is extremely corrosive
- NH₄NO₃ is an oxidizer
- Wear goggles and gloves
आवश्यक PPE
सामग्री
-
Sodium hydroxide pellets (10 g)Exothermic
-
Calcium chloride (10 g)Exothermic
-
Ammonium nitrate (10 g)Endothermic
-
Potassium nitrate (10 g)Endothermic
-
Distilled water (400 mL)
उपकरण
प्रक्रिया
Add 100 mL water to each of four labeled cups. Record the initial temperature of each.
Add 10 g NaOH to cup 1. Stir and record the maximum temperature.
Add 10 g CaCl₂ to cup 2. Stir and record the maximum temperature.
Add 10 g NH₄NO₃ to cup 3. Stir and record the minimum temperature.
Add 10 g KNO₃ to cup 4. Stir and record the minimum temperature.
Create a table ranking the salts from most exothermic to most endothermic.
Discuss why some dissolve exothermically and others endothermically (lattice energy vs hydration energy).
अपेक्षित परिणाम
NaOH: +15-20°C rise. CaCl₂: +10-15°C rise. NH₄NO₃: -15-20°C drop. KNO₃: -5-10°C drop. Clear demonstration that dissolution can be either exothermic or endothermic.
सफाई
NaOH and CaCl₂ solutions should be neutralized before disposal. All solutions can be poured down the drain after dilution.
विवरण
- श्रेणी
- Thermochemistry
- कठिनाई
- Beginner (Middle School)
- अवधि
- 25 मिनट
- अनुमानित लागत
- $8.00
- चरण
- 7
- सामग्री
- 5