Adsorção em Carvão Ativado para Purificação de Água e Ar
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O material adsorvente mais versátil da natureza
Visão geral
Activated carbon is produced by thermal or chemical activation of carbonaceous materials (coconut shell, coal, wood) to create an extremely porous material with surface areas of 800-1,500 m2/g. The vast internal surface adsorbs organic contaminants, chlorine, odors, and certain heavy metals from water and air. Activated carbon is used in municipal water treatment, industrial wastewater polishing, air purification, gas masks, gold recovery, and food/beverage decolorization.
Processo químico
Raw material (coconut shell, bituminous coal, or wood) is carbonized at 600-900 degrees C in an inert atmosphere. The char is then activated by steam or CO2 at 800-1,100 degrees C, which selectively gasifies carbon to create micropores (<2 nm) and mesopores (2-50 nm). Chemical activation uses ZnCl2 or H3PO4 at lower temperatures (400-600 degrees C). The activated carbon is washed, dried, and sized.
C + CO2 ->[800-1,100 degrees C] 2CO (CO2 activation)
Adsorption is physical (van der Waals) -- not a chemical reaction
Matérias-primas
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Coconut shell — Copra industry byproduct (SE Asia, India) (Carbon source (produces microporous AC))
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Bituminous coal — Coal mining (Carbon source (general purpose AC))
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Steam (H2O) — Boiler systems (Physical activation agent)
Produtos finais
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Granular activated carbon (GAC) — Water treatment filters, air purification (Surface area 800-1,500 m2/g, iodine number 900-1,200)
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Powdered activated carbon (PAC) — Batch water treatment, decolorization (Particle size <100 mesh)
Environmental Impact
Activated carbon production from coal consumes non-renewable resources and produces CO2. Coconut shell-based AC is more sustainable. Spent activated carbon from water treatment may contain concentrated contaminants and requires thermal reactivation or proper disposal. Reactivation recovers >90% of adsorption capacity.
Considerações de segurança
- ⚠ Activated carbon dust is a fire and explosion hazard
- ⚠ Wet AC depletes oxygen in confined spaces (adsorbs O2)
- ⚠ Thermal reactivation releases adsorbed contaminants -- emission controls required
- ⚠ Chemical activation with ZnCl2 produces toxic zinc fumes
Inovações recentes
Biochars from agricultural waste (rice husk, corn stover) provide low-cost AC alternatives for developing countries.
Magnetic activated carbon enables easy separation from water.
Activated carbon fiber cloths offer faster kinetics and lower pressure drop than granular AC in air purification.
Escala de produção
4500000
toneladas/ano
$7 billion
valor de mercado
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