Copper Displaced by Iron
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Fe + Cu2+ → Fe2+ + Cu
Visão geral
Iron reduces copper(II) ions to metallic copper while being oxidized to iron(II). This reaction proceeds because iron has a more negative standard reduction potential (-0.44 V) than copper (+0.34 V), making it a stronger reducing agent. The net cell potential is +0.78 V.
Participantes
Exemplo do cotidiano
Inserting an iron nail into blue copper sulfate solution shows copper plating on the nail as the solution loses its blue color.
Importância industrial
A cementação do cobre por ferro a partir de águas de mina é um método económico de recuperação de cobre. A compreensão dos potenciais de elétrodo é fundamental para a eletroquímica.
Propriedades
- Tipo
- Redox
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -152,3 kJ/mol