Hydrogen Sulfide Oxidation by Chlorine
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H2S + Cl2 → 2HCl + S
Visão geral
Chlorine oxidizes hydrogen sulfide to elemental sulfur while being reduced to hydrochloric acid. Sulfur is oxidized from -2 to 0. This reaction is used in removing hydrogen sulfide from natural gas (sweetening) and in treating hydrogen sulfide-containing wastewater.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Reagente | Hydrogen Sulfide H₂S | 1 | (g) |
| Reagente | Chlorine Cl | 1 | (g) |
| Produto | Sulfur S | 1 | (s) |
| Produto | Hydrochloric Acid HCl | 2 | (g) |
Exemplo do cotidiano
The rotten egg smell of hydrogen sulfide from sewers can be eliminated by chlorination, which oxidizes H₂S to odorless elemental sulfur.
Importância industrial
A remoção de H₂S por oxidação com cloro é utilizada no adoçamento do gás natural, no tratamento de águas residuais e na indústria petrolífera. Os gases com H₂S são obrigatoriamente tratados antes de serem libertados para a atmosfera.
Propriedades
- Tipo
- Redox
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -186,0 kJ/mol