Lead Sulfate Precipitation
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Pb(NO3)2 + Na2SO4 → PbSO4↓ + 2NaNO3
Visão geral
Lead nitrate reacts with sodium sulfate to form a white precipitate of lead sulfate (Ksp = 2.5 × 10⁻⁸). PbSO₄ is the discharged form of lead-acid battery electrodes. The mineral form is anglesite, named after Anglesey in Wales.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Reagente | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
| Produto | Sodium Nitrate NaNO₃ | 2 | (aq) |
Exemplo do cotidiano
When a car battery dies, both electrodes have converted to lead sulfate in a process called sulfation, which is reversed by charging.
Importância industrial
A formação de sulfato de chumbo limita a capacidade das baterias de chumbo-ácido. Compreender e prevenir a sulfatação é fundamental para a longevidade das baterias.
Propriedades
- Tipo
- Precipitation
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -19,0 kJ/mol