Oxidation of Ethanol to Acetaldehyde
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C2H5OH + [O] → CH3CHO + H2O
Visão geral
Ethanol is oxidized to acetaldehyde, with the carbon bearing the OH group changing oxidation state from -1 to +1. In the body, this reaction is catalyzed by alcohol dehydrogenase in the liver. Acetaldehyde is toxic and is responsible for many hangover symptoms.
Participantes
Exemplo do cotidiano
When you drink alcohol, your liver enzymes perform this oxidation to break down ethanol. Acetaldehyde buildup causes hangover symptoms like headache and nausea.
Importância industrial
A oxidação industrial de etanol a acetaldeído (o processo Wacker utiliza catalisador de PdCl₂ com etileno) produz um intermediário essencial para ácido acético e outros compostos químicos.
Propriedades
- Tipo
- Redox
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -175,0 kJ/mol
- Catalisador
- Alcohol dehydrogenase (in liver)