Copper Displaced by Iron
Fe + Cu2+ → Fe2+ + Cu
Overview
Iron reduces copper(II) ions to metallic copper while being oxidized to iron(II). This reaction proceeds because iron has a more negative standard reduction potential (-0.44 V) than copper (+0.34 V), making it a stronger reducing agent. The net cell potential is +0.78 V.
Participants
Everyday Example
Inserting an iron nail into blue copper sulfate solution shows copper plating on the nail as the solution loses its blue color.
Industrial Importance
Iron cementation of copper from mine waters is a cost-effective copper recovery method. Understanding electrode potentials is fundamental to electrochemistry.
Properties
- Type
- Redox
- Reversible
- No
- Energy
- Exothermic
- ΔH
- -152.3 kJ/mol
Related Reactions
Aqua Regia Dissolving Gold
Bleaching with Sodium Hypochlorite
Cerium(IV) Reduction by Iron(II)
Chlorine Oxidation of Bromide
Chromate-Dichromate Equilibrium
Contact Process SO₂ Oxidation
Copper Oxidation by Nitric Acid
Copper Patina Formation (Verdigris)
Copper Reduction of Silver Ion
Dichromate Oxidation of Ethanol
Frequently Asked Questions
What is the equation for Copper Displaced by Iron?
The balanced equation is: Fe + Cu²⁺ → Fe²⁺ + Cu.
What type of reaction is Copper Displaced by Iron?
Copper Displaced by Iron is a redox reaction.
Is Copper Displaced by Iron exothermic or endothermic?
Copper Displaced by Iron is exothermic (releases energy). The enthalpy change (ΔH) is -152.3 kJ/mol.