Decomposition of Calcium Carbonate (Calcination)
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CaCO3 → CaO + CO2
Overview
Calcium carbonate (limestone) decomposes when heated above 840 C into calcium oxide (quicklime) and carbon dioxide gas. This is one of the oldest known industrial chemical reactions, used for thousands of years in cement and mortar production. It is a key process in the cement industry.
Participants
| Role | Substance | Coefficient | State |
|---|---|---|---|
| Reactant | Calcium Carbonate CaCO₃ | 1 | (s) |
| Product | Calcium Oxide CaO | 1 | (s) |
| Product | Carbon Dioxide CO₂ | 1 | (g) |
Everyday Example
Lime kilns that have operated for centuries use this reaction to convert limestone into quicklime for building materials.
Industrial Importance
This reaction is fundamental to cement production (over 4 billion tonnes annually). It is also the largest single industrial source of CO2 emissions, responsible for about 8% of global emissions.
Properties
- Type
- Decomposition
- Reversible
- Yes
- Energy
- Endothermic
- ΔH
- 178.3 kJ/mol