Polymerization of Styrene to Polystyrene

nC₈H₈ → (–CH₂–CH(C₆H₅)–)_n

Overview

Styrene undergoes free radical addition polymerization to form polystyrene. The vinyl group polymerizes while the pendant phenyl groups provide rigidity and transparency. Expanded polystyrene (EPS) foam is produced by incorporating a blowing agent during polymerization.

Everyday Example

Styrofoam cups, food containers, packing peanuts, and insulation boards are all expanded polystyrene from this polymerization.

Industrial Importance

Over 15 million tonnes of polystyrene are produced annually for packaging, insulation, disposable cutlery, and electronics housings.

Properties

Type: Organic
Reversible: No
Energy: Exothermic
ΔH: -73.0 kJ/mol
Catalyst: Benzoyl peroxide or AIBN

Related Reactions

Aldol Condensation of Acetaldehyde Amide Formation (Acetic Acid + Ammonia) Baeyer-Villiger Oxidation Beckmann Rearrangement (Cyclohexanone Oxime) Bromination of Ethylene Buchwald-Hartwig Amination Cannizzaro Reaction of Formaldehyde Catalytic Hydrogenation of Ethylene Claisen Condensation (Ethyl Acetate) Condensation Polymerization (Nylon 6,6)

Frequently Asked Questions

What is the equation for Polymerization of Styrene to Polystyrene?

The balanced equation is: nC₈H₈ → (–CH₂–CH(C₆H₅)–)ₙ.

What type of reaction is Polymerization of Styrene to Polystyrene?

Polymerization of Styrene to Polystyrene is a organic reaction.

Is Polymerization of Styrene to Polystyrene exothermic or endothermic?

Polymerization of Styrene to Polystyrene is exothermic (releases energy). The enthalpy change (ΔH) is -73.0 kJ/mol.

What conditions are needed for Polymerization of Styrene to Polystyrene?

This reaction requires a catalyst (Benzoyl peroxide or AIBN).