Contact Process SO₂ Oxidation
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2SO2 + O2 ⇌ 2SO3
نظرة عامة
Sulfur dioxide is oxidized to sulfur trioxide over a vanadium pentoxide catalyst in the contact process for sulfuric acid manufacture. Sulfur changes from +4 to +6 oxidation state. The equilibrium is favored by low temperature but requires high temperature for adequate reaction rate, so 400-450 C with V₂O₅ catalyst provides optimal yield.
المشاركون
| الدور | المادة | المعامل | الحالة |
|---|---|---|---|
| متفاعل | Oxygen O | 1 | (g) |
| متفاعل | Sulfur Dioxide SO₂ | 2 | (g) |
| منتج | Sulfur Trioxide SO₃ | 2 | (g) |
مثال من الحياة اليومية
Sulfuric acid produced by this process is the world's most produced chemical, used in everything from fertilizers to batteries to detergents.
الأهمية الصناعية
The contact process produces over 260 million tonnes of sulfuric acid annually. V₂O₅ catalyst replaced the original, more expensive platinum catalyst.
الخصائص
- النوع
- Redox
- قابل للعكس
- نعم
- الطاقة
- طارد للحرارة
- ΔH
- -198,0 kJ/mol
- محفز
- Vanadium(V) oxide (V₂O₅)