Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)
PbO2 + Pb + 2H2SO4 → 2PbSO4 + 2H2O
نظرة عامة
During discharge, lead dioxide (cathode, Pb⁴⁺) is reduced to lead sulfate while lead metal (anode, Pb⁰) is oxidized to lead sulfate. Both electrodes convert to PbSO₄, and the sulfuric acid electrolyte is consumed. The cell potential is 2.05 V. Charging reverses the reaction.
المشاركون
| الدور | المادة | المعامل | الحالة |
|---|---|---|---|
| متفاعل | Lead Pb | 1 | (s) |
| متفاعل | Sulfuric Acid H₂SO₄ | 2 | (aq) |
| منتج | Water H₂O | 2 | (l) |
مثال من الحياة اليومية
Every car battery is a lead-acid battery using this reversible redox reaction. Starting your car draws hundreds of amps from this reaction.
الأهمية الصناعية
Lead-acid batteries represent a $40+ billion global industry used in vehicles, UPS systems, and energy storage. Over 99% of lead-acid batteries are recycled.
الخصائص
- النوع
- Redox
- قابل للعكس
- نعم
- الطاقة
- طارد للحرارة
- ΔH
- -359,4 kJ/mol
التفاعلات ذات الصلة
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)?
The balanced equation is: PbO₂ + Pb + 2H₂SO₄ → 2PbSO₄ + 2H₂O.
What type of reaction is Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)?
Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) is a redox reaction. It is reversible under certain conditions.
Is Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) exothermic or endothermic?
Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) is exothermic (releases energy). The enthalpy change (ΔH) is -359.4 kJ/mol.