Synthesis of Acetic Acid (Monsanto Process)
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CH3OH + CO → CH3COOH
نظرة عامة
Methanol reacts with carbon monoxide in the presence of a rhodium-iodide catalyst to form acetic acid. The Monsanto process (and its successor, the Cativa process using iridium) is the dominant industrial method for acetic acid production.
المشاركون
| الدور | المادة | المعامل | الحالة |
|---|---|---|---|
| متفاعل | Methanol CH₃OH | 1 | (l) |
| متفاعل | Carbon Monoxide CO | 1 | (g) |
| منتج | Acetic Acid CH₃COOH | 1 | (l) |
مثال من الحياة اليومية
White vinegar contains approximately 5% acetic acid, though commercial vinegar is typically produced by fermentation rather than this industrial process.
الأهمية الصناعية
Over 16 million tonnes of acetic acid are produced annually using this process. Acetic acid is used to make vinyl acetate, acetic anhydride, cellulose acetate, and as a solvent.
الخصائص
- النوع
- Synthesis
- قابل للعكس
- لا
- الطاقة
- طارد للحرارة
- ΔH
- -138,6 kJ/mol
- محفز
- Rhodium/iodide complex