Chromium(III) Hydroxide Precipitation

CrCl3 + 3NaOH → Cr(OH)3↓ + 3NaCl

Aperçu

Chromium(III) chloride reacts with sodium hydroxide to form a green gelatinous precipitate of chromium(III) hydroxide (Ksp = 6.3 × 10⁻³¹). Cr(OH)₃ is amphoteric, dissolving in both excess acid and excess NaOH. In excess NaOH, it forms the green chromite ion [Cr(OH)₄]⁻.

Participants

Rôle Substance Coefficient État
Réactif Sodium Hydroxide NaOH 3 (aq)
Produit Sodium Chloride NaCl 3 (aq)

Exemple du quotidien

The green color of some gemstones like emerald is due to chromium(III) ions, the same oxidation state that produces this green precipitate.

Importance industrielle

Chromium(III) hydroxide precipitation is used in chromium removal from industrial wastewater, particularly from chrome plating and leather tanning effluents.

Frequently Asked Questions

What is the equation for Chromium(III) Hydroxide Precipitation?
The balanced equation is: CrCl₃ + 3NaOH → Cr(OH)₃↓ + 3NaCl.
What type of reaction is Chromium(III) Hydroxide Precipitation?
Chromium(III) Hydroxide Precipitation is a precipitation reaction.
Is Chromium(III) Hydroxide Precipitation exothermic or endothermic?
Chromium(III) Hydroxide Precipitation is exothermic (releases energy). The enthalpy change (ΔH) is -90.0 kJ/mol.