Iron(III) Hydroxide Precipitation
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FeCl3 + 3NaOH → Fe(OH)3↓ + 3NaCl
Aperçu
Iron(III) chloride reacts with sodium hydroxide to form a rust-brown gelatinous precipitate of iron(III) hydroxide. Fe(OH)₃ has an extremely low Ksp of 2.8 × 10⁻³⁹, precipitating even at slightly acidic pH. The gelatinous nature makes it an excellent flocculant for water treatment.
Participants
| Rôle | Substance | Coefficient | État |
|---|---|---|---|
| Réactif | Iron(III) Chloride FeCl₃ | 1 | (aq) |
| Réactif | Sodium Hydroxide NaOH | 3 | (aq) |
| Produit | Sodium Chloride NaCl | 3 | (aq) |
Exemple du quotidien
The rust-colored sludge in water treatment plants is mainly iron(III) hydroxide precipitated by adding base to iron-rich water.
Importance industrielle
Iron(III) hydroxide precipitation is the primary method for iron removal from drinking water and is used as a coagulant in wastewater treatment.
Propriétés
- Type
- Precipitation
- Réversible
- Non
- Énergie
- Exothermique
- ΔH
- -88,0 kJ/mol