Pasta de Dente de Elefante
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Decomposição catalítica rápida do peróxido de hidrogênio produzindo uma enorme coluna de espuma
Objetivo
Demonstrar a decomposição catalítica do peróxido de hidrogênio usando iodeto de potássio, ilustrando conceitos de catálise, reações exotérmicas e evolução de gases.
Contexto
Elephant toothpaste is one of the most popular chemistry demonstrations. Concentrated hydrogen peroxide (H₂O₂) is decomposed rapidly by a potassium iodide (KI) catalyst, releasing oxygen gas and steam. When performed in a narrow-neck flask with dish soap, the oxygen gas creates a towering column of foam that erupts like giant toothpaste. The reaction is exothermic, and the foam is warm to the touch. The iodide ion acts as a catalyst by cycling between I⁻ and IO⁻ intermediates.
Avisos de segurança
- 30% H₂O₂ causes severe skin burns and eye damage
- Wear face shield and heavy-duty gloves
- Do not stand over the flask when adding KI
- The foam is hot — do not touch immediately
- Perform behind a safety shield
EPI necessário
Materiais
-
Hydrogen peroxide (30%) (50 mL)30% concentration required for dramatic effect
-
Potassium iodide (KI) (10 g)Dissolved in 25 mL water
-
Liquid dish soap (15 mL)
-
Food coloring (5 drops)Optional, for visual effect
-
Large tray or bin (1)To catch overflow
Equipamentos
Procedimento
Place the Erlenmeyer flask on the large tray. Set up the safety shield.
Carefully pour 50 mL of 30% H₂O₂ into the flask.
Add 15 mL of dish soap and a few drops of food coloring. Swirl gently to mix.
Dissolve 10 g of KI in 25 mL of warm water. Pour this solution into the flask using a funnel and step back immediately.
Observe the rapid evolution of foam. The reaction is complete in seconds. Discuss the role of KI as a catalyst.
After the foam cools, students may touch it (with gloves). It contains only water, oxygen, soap, and KI — no H₂O₂ remains.
Resultados esperados
A dramatic eruption of warm, colored foam that rises 1–2 meters above the flask. Steam may be visible. The reaction demonstrates catalysis (KI is not consumed), exothermic processes, and gas evolution (O₂).
Limpeza
The foam is non-toxic (soap, water, KI). Rinse down the drain with plenty of water. Clean the flask and tray.
Detalhes
- Categoria
- Classroom Demonstrations
- Dificuldade
- Beginner (Middle School)
- Duração
- 20 min
- Custo estimado
- $10,00
- Passos
- 6
- Materiais
- 5