Methanol Oxidation to Formaldehyde
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2CH3OH + O2 → 2HCHO + 2H2O
Visão geral
Methanol is oxidized to formaldehyde by oxygen over a metal oxide catalyst. The carbon oxidation state changes from -2 in methanol to 0 in formaldehyde. This catalytic partial oxidation is the primary industrial route to formaldehyde, the simplest aldehyde.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Reagente | Oxygen O | 1 | (g) |
| Reagente | Methanol CH₃OH | 2 | (l) |
| Produto | Formaldehyde CH₂O | 2 | (g) |
| Produto | Water H₂O | 2 | (l) |
Exemplo do cotidiano
Formaldehyde is used in particleboard and MDF manufacturing, and its solutions (formalin) were historically used to preserve biological specimens.
Importância industrial
São produzidas mais de 50 milhões de toneladas de formaldeído por ano para resinas (ureia-formaldeído, fenol-formaldeído), plásticos e como intermediário químico.
Propriedades
- Tipo
- Redox
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -323,0 kJ/mol
- Catalisador
- Silver or iron-molybdenum oxide