Permanganate Oxidation of Iron(II)
MnO4− + 5Fe2+ + 8H+ → Mn2+ + 5Fe3+ + 4H2O
Visão geral
Permanganate ion is a powerful oxidizing agent that oxidizes iron(II) to iron(III) while being reduced from Mn(VII) to Mn(II) in acidic solution. The dramatic color change from deep purple KMnO₄ to nearly colorless Mn²⁺ makes this reaction self-indicating in titrations.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Produto | Water H₂O | 4 | (l) |
Exemplo do cotidiano
Potassium permanganate's purple color is used in water purification systems and as a disinfectant for fruits and vegetables in some countries.
Importância industrial
A titulação com permanganato (permanganometria) é um método analítico padrão para determinar o teor de ferro em minérios, água e amostras ambientais.
Propriedades
- Tipo
- Redox
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -536,0 kJ/mol
Reações relacionadas
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Permanganate Oxidation of Iron(II)?
The balanced equation is: MnO₄⁻ + 5Fe²⁺ + 8H⁺ → Mn²⁺ + 5Fe³⁺ + 4H₂O.
What type of reaction is Permanganate Oxidation of Iron(II)?
Permanganate Oxidation of Iron(II) is a redox reaction.
Is Permanganate Oxidation of Iron(II) exothermic or endothermic?
Permanganate Oxidation of Iron(II) is exothermic (releases energy). The enthalpy change (ΔH) is -536.0 kJ/mol.