Thermal Decomposition of Lead(IV) Oxide
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2PbO2 → 2PbO + O2
Visão geral
Lead(IV) oxide (lead dioxide) decomposes when heated above 290 C to form lead(II) oxide and oxygen. This decomposition reflects the instability of the +4 oxidation state for lead. Lead dioxide is a strong oxidizer used in lead-acid batteries.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Produto | Oxygen O | 1 | (g) |
Exemplo do cotidiano
The positive plates of car batteries contain lead dioxide, which undergoes reduction (not this thermal decomposition) during discharge.
Importância industrial
Compreender a estabilidade do PbO₂ é fundamental para o design de baterias de chumbo-ácido. O dióxido de chumbo é também utilizado como material de elétrodo no tratamento de água e síntese química.
Propriedades
- Tipo
- Decomposition
- Reversível
- Não
- Energia
- Endotérmico
- ΔH
- 118,4 kJ/mol