Cadmium Sulfide Precipitation (Yellow)
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CdCl2 + Na2S → CdS↓ + 2NaCl
Overview
Cadmium chloride reacts with sodium sulfide to form a bright yellow precipitate of cadmium sulfide (Ksp = 8 × 10⁻²⁷). CdS is known as cadmium yellow and was historically an important artist's pigment. The brilliant yellow color is due to its 2.4 eV bandgap.
Participants
| Role | Substance | Coefficient | State |
|---|---|---|---|
| Product | Sodium Chloride NaCl | 2 | (aq) |
Everyday Example
Many of Claude Monet's and Vincent van Gogh's paintings feature cadmium yellow pigment, prized for its brilliance and light-fastness.
Industrial Importance
CdS is used as a pigment, in photocells and light meters, in thin-film solar cells (CdTe/CdS), and as a quantum dot material.
Properties
- Type
- Precipitation
- Reversible
- No
- Energy
- Exothermic
- ΔH
- -78.0 kJ/mol