Chlorophyll Fluorescence
Chlorophyll + hν (blue/red) → Chlorophyll* → Chlorophyll + hν (red)
Overview
Chlorophyll absorbs blue (430 nm) and red (660 nm) light, reaching an excited singlet state. Most energy is transferred to the photosynthetic reaction center, but a small fraction (1–2%) is re-emitted as red fluorescence (680–740 nm). This fluorescence is a direct indicator of photosynthetic efficiency.
Everyday Example
If you shine a UV light on a spinach extract, it glows red due to chlorophyll fluorescence — a common chemistry demonstration.
Industrial Importance
Chlorophyll fluorescence measurement (PAM fluorometry) is used in agriculture, forestry, and ecology to assess plant health and stress.
Properties
- Type
- Photochemical
- Reversible
- Yes
- Energy
- Exothermic
Related Reactions
Cis-Trans Isomerization of Retinal
Dye-Sensitized Solar Cell (Grätzel Cell)
Firefly Bioluminescence (Luciferin Oxidation)
Luminol Chemiluminescence
Ozone Decomposition by UV
Ozone Formation by UV Light
Photocatalytic NOx Removal
Photocatalytic Water Splitting (TiO₂)
Photochemical Cycloaddition ([2+2])
Photochemical Smog Formation (NO₂ Photolysis)
Frequently Asked Questions
What is the equation for Chlorophyll Fluorescence?
The balanced equation is: Chlorophyll + hν (blue/red) → Chlorophyll* → Chlorophyll + hν (red).
What type of reaction is Chlorophyll Fluorescence?
Chlorophyll Fluorescence is a photochemical reaction. It is reversible under certain conditions.
Is Chlorophyll Fluorescence exothermic or endothermic?
Chlorophyll Fluorescence is exothermic (releases energy).