Cathodic Protection (Zinc Sacrificial Anode)
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Zn → Zn2+ + 2e−
Visão geral
A zinc sacrificial anode is electrically connected to a steel structure. Since zinc has a more negative electrode potential (-0.76 V) than iron (-0.44 V), zinc preferentially oxidizes, supplying electrons that keep the steel in its reduced (protected) state. The zinc anode is consumed over time and must be replaced.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Reagente | Zinc Zn | 1 | (s) |
Exemplo do cotidiano
Ships' hulls, water heaters, and underground pipelines all use zinc blocks bolted to steel for corrosion protection.
Importância industrial
A proteção catódica previne anualmente milhares de milhões de dólares em danos por corrosão em navios, oleodutos, pontes e plataformas offshore.
Propriedades
- Tipo
- Electrochemical
- Reversível
- Não
- Energia
- Exotérmico
- ΔH
- -147,0 kJ/mol