Thermal Decomposition of Sulfuric Acid
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H2SO4 → H2O + SO3
Visão geral
Concentrated sulfuric acid decomposes at high temperatures (above 340 C) into water vapor and sulfur trioxide gas. This is the reverse of the hydration reaction that produces sulfuric acid. The equilibrium shifts toward decomposition at high temperatures.
Participantes
| Papel | Substância | Coeficiente | Estado |
|---|---|---|---|
| Reagente | Sulfuric Acid H₂SO₄ | 1 | (l) |
| Produto | Water H₂O | 1 | (g) |
| Produto | Sulfur Trioxide SO₃ | 1 | (g) |
Exemplo do cotidiano
This decomposition is relevant to understanding why concentrated sulfuric acid fumes in hot weather and must be stored properly.
Importância industrial
Este equilíbrio é importante nos processos de concentração de ácido sulfúrico e nos processos de câmara de chumbo e de contacto para fabrico de ácido sulfúrico.
Propriedades
- Tipo
- Decomposition
- Reversível
- Sim
- Energia
- Endotérmico
- ΔH
- 177,0 kJ/mol