Synthesis of Acetic Acid (Monsanto Process)
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CH3OH + CO → CH3COOH
Обзор
Methanol reacts with carbon monoxide in the presence of a rhodium-iodide catalyst to form acetic acid. The Monsanto process (and its successor, the Cativa process using iridium) is the dominant industrial method for acetic acid production.
Участники
| Роль | Вещество | Коэффициент | Состояние |
|---|---|---|---|
| Реагент | Methanol CH₃OH | 1 | (l) |
| Реагент | Carbon Monoxide CO | 1 | (g) |
| Продукт | Acetic Acid CH₃COOH | 1 | (l) |
Пример из жизни
White vinegar contains approximately 5% acetic acid, though commercial vinegar is typically produced by fermentation rather than this industrial process.
Промышленное значение
Over 16 million tonnes of acetic acid are produced annually using this process. Acetic acid is used to make vinyl acetate, acetic anhydride, cellulose acetate, and as a solvent.
Свойства
- Тип
- Synthesis
- Обратимая
- Нет
- Энергия
- Экзотермическая
- ΔH
- -138,6 kJ/mol
- Катализатор
- Rhodium/iodide complex