Barium Hydroxide and Ammonium Thiocyanate (Endothermic)
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Ba(OH)2·8H2O + 2NH4SCN → Ba(SCN)2 + 2NH3 + 10H2O
نظرة عامة
This highly endothermic acid-base reaction absorbs so much heat that it can freeze water beneath the flask. Mixing barium hydroxide octahydrate with ammonium thiocyanate drops the temperature below -20 C. The ammonium ion acts as a weak acid donating protons to hydroxide.
المشاركون
مثال من الحياة اليومية
This is one of the most dramatic endothermic reaction demonstrations, where a wet board freezes to a beaker as the reaction proceeds.
الأهمية الصناعية
This reaction is primarily used as a teaching demonstration of endothermic processes and entropy-driven reactions, illustrating the thermodynamics concept that ΔG = ΔH - TΔS.
الخصائص
- النوع
- Acid-Base
- قابل للعكس
- لا
- الطاقة
- ماص للحرارة
- ΔH
- 170,0 kJ/mol