瞬間凍結:過冷却水
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過冷却水の瞬間的な結晶化を引き起こす
目的
精製水を凍結せずに0°C以下に冷却して過冷却を実証し、瞬間的な結晶化を引き起こす。
背景
Pure water can be cooled below its freezing point (0°C) without solidifying if there are no nucleation sites for ice crystals to form. This metastable state, called supercooling, can persist down to about −40°C for very pure water. When a supercooled sample is disturbed (tapped, shaken, or a small ice crystal is added), crystallization cascades through the entire sample in seconds, creating a dramatic visual effect.
安全上の警告
- Handle glass thermometers with care
- Do not use glass bottles — they may shatter if water freezes and expands
- Supercooled water will freeze instantly if disturbed — handle very gently
必要なPPE
材料
-
Purified water (distilled or deionized) (500 mL)Must be very pure
-
Clean plastic bottles (5)New, unopened, smooth interior
-
Small ice crystal (1)Nucleation seed
-
Thermometer (−20 to 10°C) (1)
器具
手順
Place 5 sealed bottles of purified water in the freezer, undisturbed. Set a timer for 90 minutes (adjust based on freezer temperature).
Very carefully remove one bottle. If it is still liquid and the temperature reads below 0°C, it is supercooled.
Method 1 (Impact nucleation): Sharply tap the bottle on a table. Watch ice crystals propagate through the liquid.
Method 2 (Seed crystal): Carefully open a second supercooled bottle and drop a small ice chip in. Watch instant freezing from the crystal seed.
Method 3 (Pour): Slowly pour supercooled water onto an ice cube in a bowl. Watch an ice tower build up.
Discuss nucleation, supercooling, and phase transitions. Explain why purity and smooth container walls are essential.
予想される結果
The water remains liquid below 0°C until disturbed. Upon nucleation, ice crystals propagate visibly through the bottle in 2–5 seconds. Pouring onto an ice cube creates a growing column of ice.
後片付け
Thaw any frozen bottles. No chemical waste. Return thermometer to storage.
詳細
- 難易度
- Beginner (Middle School)
- 所要時間
- 120 分
- 推定費用
- $3.00
- ステップ数
- 6
- 材料
- 4