Chromium(III) Hydroxide Precipitation
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CrCl3 + 3NaOH → Cr(OH)3↓ + 3NaCl
概要
Chromium(III) chloride reacts with sodium hydroxide to form a green gelatinous precipitate of chromium(III) hydroxide (Ksp = 6.3 × 10⁻³¹). Cr(OH)₃ is amphoteric, dissolving in both excess acid and excess NaOH. In excess NaOH, it forms the green chromite ion [Cr(OH)₄]⁻.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide NaOH | 3 | (aq) |
| 生成物 | Sodium Chloride NaCl | 3 | (aq) |
日常の例
The green color of some gemstones like emerald is due to chromium(III) ions, the same oxidation state that produces this green precipitate.
産業上の重要性
水酸化クロム(III)沈殿は、特にクロムメッキや皮革なめしの排水から、工業排水中のクロムを除去するために使用されています。
特性
- タイプ
- Precipitation
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -90.0 kJ/mol