Lead Carbonate Precipitation
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Pb(NO3)2 + Na2CO3 → PbCO3↓ + 2NaNO3
概要
Lead nitrate reacts with sodium carbonate to form a white precipitate of lead carbonate (Ksp = 7.4 × 10⁻¹⁴). Basic lead carbonate (2PbCO₃·Pb(OH)₂), known as white lead, was the most important white pigment for millennia until its toxicity led to replacement by titanium dioxide.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Sodium Carbonate Na₂CO₃ | 1 | (aq) |
| 生成物 | Sodium Nitrate NaNO₃ | 2 | (aq) |
日常の例
White lead paint was used in homes for centuries before being banned due to lead poisoning, especially dangerous for children.
産業上の重要性
炭酸鉛(鉛白)は塗料でTiO₂に置き換えられた。鉛沈殿の理解は廃水処理、土壌浄化、旧来の鉛配管からの鉛汚染対策に現在も重要である。
特性
- タイプ
- Precipitation
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -22.0 kJ/mol