Electrolytic Production of Chlorate
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NaCl + 3H2O → NaClO3 + 3H2
Обзор
Electrolysis of hot NaCl solution without a membrane allows chlorine produced at the anode to react with hydroxide from the cathode, forming hypochlorite that disproportionates to chlorate at 70–80°C. Sodium chlorate (NaClO₃) is the precursor to chlorine dioxide (ClO₂), the dominant bleaching agent in modern paper mills.
Участники
| Роль | Вещество | Коэффициент | Состояние |
|---|---|---|---|
| Реагент | Sodium Chloride NaCl | 1 | (aq) |
| Реагент | Water H₂O | 3 | (l) |
Пример из жизни
The white paper in your books and notebooks was bleached using chlorine dioxide derived from electrolytically produced sodium chlorate.
Промышленное значение
About 3.6 million tonnes of sodium chlorate are produced annually, primarily for pulp bleaching, herbicides, and water treatment.
Свойства
- Тип
- Electrochemical
- Обратимая
- Нет
- Энергия
- Эндотермическая
- ΔH
- 590,0 kJ/mol