Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)
PbO2 + Pb + 2H2SO4 → 2PbSO4 + 2H2O
Обзор
During discharge, lead dioxide (cathode, Pb⁴⁺) is reduced to lead sulfate while lead metal (anode, Pb⁰) is oxidized to lead sulfate. Both electrodes convert to PbSO₄, and the sulfuric acid electrolyte is consumed. The cell potential is 2.05 V. Charging reverses the reaction.
Участники
| Роль | Вещество | Коэффициент | Состояние |
|---|---|---|---|
| Реагент | Lead Pb | 1 | (s) |
| Реагент | Sulfuric Acid H₂SO₄ | 2 | (aq) |
| Продукт | Water H₂O | 2 | (l) |
Пример из жизни
Every car battery is a lead-acid battery using this reversible redox reaction. Starting your car draws hundreds of amps from this reaction.
Промышленное значение
Lead-acid batteries represent a $40+ billion global industry used in vehicles, UPS systems, and energy storage. Over 99% of lead-acid batteries are recycled.
Свойства
- Тип
- Redox
- Обратимая
- Да
- Энергия
- Экзотермическая
- ΔH
- -359,4 kJ/mol
Связанные реакции
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)?
The balanced equation is: PbO₂ + Pb + 2H₂SO₄ → 2PbSO₄ + 2H₂O.
What type of reaction is Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge)?
Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) is a redox reaction. It is reversible under certain conditions.
Is Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) exothermic or endothermic?
Lead Dioxide and Sulfuric Acid (Lead-Acid Battery Discharge) is exothermic (releases energy). The enthalpy change (ΔH) is -359.4 kJ/mol.