Polymerization of Vinyl Chloride to PVC

nCH2=CHCl → (–CH2–CHCl–)n

概要

Vinyl chloride monomer (VCM) undergoes free radical addition polymerization to form polyvinyl chloride (PVC), the third most produced plastic worldwide. PVC is rigid by default but can be made flexible with plasticizers. Suspension polymerization is the most common industrial method.

日常の例

PVC pipes, vinyl flooring, window frames, wire insulation, and credit cards are all made from this polymerization reaction.

産業上の重要性

PVCは建設、医療、自動車、包装用途として年間4,500万トン以上生産される。

特性

タイプ
Organic
可逆的
いいえ
エネルギー
発熱性
ΔH
-72.0 kJ/mol
触媒
Free radical initiators

関連する反応

Swern Oxidation Oxidation of Secondary Alcohol to Ketone Claisen Condensation (Ethyl Acetate) Kolbe Electrolysis Baeyer-Villiger Oxidation Beckmann Rearrangement (Cyclohexanone Oxime) Catalytic Hydrogenation of Ethylene Condensation Polymerization (Nylon 6,6) Cope Rearrangement Epoxidation of Alkenes (mCPBA)

Frequently Asked Questions

What is the equation for Polymerization of Vinyl Chloride to PVC?
The balanced equation is: nCH₂=CHCl → (–CH₂–CHCl–)ₙ.
What type of reaction is Polymerization of Vinyl Chloride to PVC?
Polymerization of Vinyl Chloride to PVC is a organic reaction.
Is Polymerization of Vinyl Chloride to PVC exothermic or endothermic?
Polymerization of Vinyl Chloride to PVC is exothermic (releases energy). The enthalpy change (ΔH) is -72.0 kJ/mol.
What conditions are needed for Polymerization of Vinyl Chloride to PVC?
This reaction requires a catalyst (Free radical initiators).