Silver Chloride Precipitation
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AgNO3 + NaCl → AgCl↓ + NaNO3
概要
Silver nitrate reacts with sodium chloride to form a white curdy precipitate of silver chloride. AgCl has a very low Ksp of 1.8 × 10⁻¹⁰, making it essentially insoluble. The precipitate turns purple in light due to photodecomposition of AgCl to silver metal and chlorine. This is the basis of the chloride ion test.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Silver Nitrate AgNO₃ | 1 | (aq) |
| 反応物 | Sodium Chloride NaCl | 1 | (aq) |
| 生成物 | Silver Chloride AgCl | 1 | (s) |
| 生成物 | Sodium Nitrate NaNO₃ | 1 | (aq) |
日常の例
The silver chloride test for chloride ions in water is one of the first qualitative analysis tests taught in chemistry courses.
産業上の重要性
AgCl沈殿は水質検査、写真(歴史的)、電気化学用塩化銀電極の調製に使用される。
特性
- タイプ
- Precipitation
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -65.5 kJ/mol