Zinc Hydroxide Precipitation
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ZnSO4 + 2NaOH → Zn(OH)2↓ + Na2SO4
概要
Zinc sulfate reacts with sodium hydroxide to form a white gelatinous precipitate of zinc hydroxide (Ksp = 3.0 × 10⁻¹⁷). Zn(OH)₂ is amphoteric, dissolving in excess NaOH to form the zincate ion [Zn(OH)₄]²⁻. This amphoteric behavior is a diagnostic test for zinc in qualitative analysis.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Zinc Sulfate ZnSO₄ | 1 | (aq) |
| 反応物 | Sodium Hydroxide NaOH | 2 | (aq) |
| 生成物 | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
日常の例
Calamine lotion contains zinc compounds that form protective precipitates on skin, soothing itching from insect bites and rashes.
産業上の重要性
水酸化亜鉛の沈殿は排水からの亜鉛回収、カラミンローションの製造、酸化亜鉛の前駆体として使用される。
特性
- タイプ
- Precipitation
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -38.0 kJ/mol