Calcium Oxalate Precipitation (Kidney Stones)
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CaCl2 + Na2C2O4 → CaC2O4↓ + 2NaCl
Обзор
Calcium chloride reacts with sodium oxalate to form a white precipitate of calcium oxalate (Ksp = 2.3 × 10⁻⁹). Calcium oxalate is the primary component of approximately 80% of kidney stones. The monohydrate form (whewellite) is thermodynamically favored and forms the hardest, most painful stones.
Участники
| Роль | Вещество | Коэффициент | Состояние |
|---|---|---|---|
| Реагент | Oxalic Acid C₂H₂O₄ | 1 | (aq) |
| Продукт | Sodium Chloride NaCl | 2 | (aq) |
Пример из жизни
Most kidney stones are calcium oxalate crystals. Foods high in oxalate (spinach, rhubarb, almonds) can increase stone risk.
Промышленное значение
Understanding calcium oxalate precipitation is critical in nephrology, food science (oxalate content analysis), and in beer brewing (beer stone prevention).
Свойства
- Тип
- Precipitation
- Обратимая
- Нет
- Энергия
- Экзотермическая
- ΔH
- -12,0 kJ/mol