Iron(II) Sulfide Precipitation
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FeSO4 + Na2S → FeS↓ + Na2SO4
Обзор
Iron(II) sulfate reacts with sodium sulfide to form a black precipitate of iron(II) sulfide (Ksp = 6 × 10⁻¹⁸). FeS reacts with dilute acids to produce hydrogen sulfide gas with its characteristic rotten egg smell. The mineral form is troilite, found in meteorites.
Участники
| Роль | Вещество | Коэффициент | Состояние |
|---|---|---|---|
| Продукт | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
Пример из жизни
The black spots in hard-boiled eggs at the yolk-white junction are iron sulfide, formed by reaction of iron in the yolk with sulfur from the egg white.
Промышленное значение
Iron sulfide is encountered in the petroleum industry as a corrosion product in sour gas wells and is the mineral pyrrhotite in geological formations.
Свойства
- Тип
- Precipitation
- Обратимая
- Нет
- Энергия
- Экзотермическая
- ΔH
- -75,0 kJ/mol