Sulfuric Acid and Calcium Carbonate
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H2SO4 + CaCO3 → CaSO4 + H2O + CO2
Обзор
Sulfuric acid reacts with calcium carbonate to form calcium sulfate, water, and carbon dioxide. Unlike HCl, this reaction can be self-limiting because the insoluble calcium sulfate coats the limestone surface, slowing further reaction. This is why HCl is preferred over H₂SO₄ for dissolving limestone.
Участники
| Роль | Вещество | Коэффициент | Состояние |
|---|---|---|---|
| Реагент | Calcium Carbonate CaCO₃ | 1 | (s) |
| Реагент | Sulfuric Acid H₂SO₄ | 1 | (aq) |
| Продукт | Carbon Dioxide CO₂ | 1 | (g) |
| Продукт | Water H₂O | 1 | (l) |
| Продукт | Calcium Sulfate CaSO₄ | 1 | (s) |
Пример из жизни
Acid rain containing sulfuric acid damages limestone buildings and marble statues through this reaction, causing surface erosion over decades.
Промышленное значение
This reaction is relevant to acid rain damage assessment, flue gas desulfurization (wet limestone scrubbing), and phosphoric acid production from phosphate rock.
Свойства
- Тип
- Acid-Base
- Обратимая
- Нет
- Энергия
- Экзотермическая
- ΔH
- -26,0 kJ/mol